Recovery Technologies
Tailings reprocessing, mineral separation and secondary resource recovery
This page answers the question that comes after “there is something in this waste”: how would anyone actually get it out? It is written for people who will judge the answer — process engineers, metallurgists, geologists, regulators and the owners of the material. There is no universal technology for mine waste, and the reason is not that nobody has invented one yet.
A recovery route is decided by the material, not by the element in the assay: mineralogy, particle size, liberation, mineral deportment, moisture, density contrast, magnetic and electrical response, surface chemistry, and what the historical plant already did to it. A technology that works beautifully on one waste body is useless on the one next to it.
The headings, summaries, maturity labels, warnings and conclusions on this page are translated. The detailed technical passages are kept in English, where the process terminology is unambiguous. Fully translated versions exist in English, Spanish and Portuguese.
Liberation, before anything else
This is the single idea that decides whether any physical separation can work, and it is the one most often skipped. A separator does not act on elements. It acts on particles, and it can only sort a particle by a property that particle actually has.
A flotation tailing contains what the plant failed to recover — and one of the commonest reasons a mineral is not recovered is that it was never liberated in the first place. So the material most likely to still hold something is also the material where physical preconcentration is least likely to work. Assuming otherwise is how a project rejects seventy per cent of its mass and seventy per cent of its metal in the same step.
Breaking rock, and where the energy goesphysical
Comminution consumes the majority of the energy a concentrator uses and a few per cent of all the electricity generated on the planet. Almost none of it goes into breaking anything: most is lost as heat and noise, and a large part of what remains breaks rock that did not need breaking. For waste reprocessing this is the difference between a project and a rounding error, because the metal is dilute and the tonnage is enormous.
Two facts drive every decision here. Grinding finer liberates more mineral and always costs more energy. And material that has already been through a mill once — which is what tailings are — does not need the coarse stages at all.
It is the one intervention guaranteed to improve liberation, which makes it the reflex. But energy per tonne rises steeply as size falls, fine particles float and settle badly, and the residue becomes a slurry that needs a dam — reintroducing the exact liability the project was meant to remove. Grinding the whole feed finer to chase a low-grade metal is how reprocessing studies die. Grinding a small pre-concentrate finer is how they survive.
Wet or dry?
Both, and the choice is not ideological. Water is not a defect — it is what keeps fine particles apart so that a separator can act on them individually.
Flotation
Reagents make the surface of one mineral water-repellent; air bubbles carry it to a froth and everything else stays behind. It remains the workhorse of sulphide processing and is actively studied for reprocessing.
Material is left behind for reasons that have nothing to do with the method being wrong: poor liberation, the reagent chemistry available at the time, the equipment of the period, a different target mineral, oxidation, or an economic cut-off that has since moved. Decades later the same family of technology can work. Historical use is a reason for caution, not a reason to rule a route out.
Gravity separation
Denser particles settle, are thrown or are carried differently. Simple, cheap in energy terms, and completely dependent on liberation.
Magnetic separation
Wet or dry, at low, high or high-gradient field. Intensity is a dial rather than a switch, and it reaches progressively weaker responses.
Electrostatic and triboelectric separation
Dry, and for that reason perennially attractive. Particles acquire opposite charges by contact and an electric field pulls them apart.
Sensor sorting
Each particle is measured — by X-ray transmission, near-infrared, optical or other sensing — and ejected mechanically.
Leaching and hydrometallurgy
Dissolve the target selectively, then recover it from solution — by precipitation, solvent extraction, ion exchange or membranes. Acid, alkaline, cyanide and chloride systems all belong to this family, as does bioleaching, where microorganisms do the mobilising.
Bioleaching can lower some chemical inputs, but it is slow, strongly material-dependent and sensitive to temperature and pH. It is not green by definition, and it is not fast.
Coarse particle recoverysurface chemistry
Conventional flotation loses particles above roughly 150 µm: a grain that heavy tears off the bubble in a turbulent cell. The industry answered that for a century by grinding finer, which is where most of the energy in a concentrator goes. Fluidised-bed flotation removes the turbulence instead — the particle sits in a quiescent rising water column, so a bubble that attaches is not shaken loose — and recovers composite grains three to five times coarser.commercial
For waste this matters more than it does for fresh ore. A coarse reject can be dewatered by screening alone and stacked dry, so a plant that recovers coarse produces a residue that does not need a dam. The trade is selectivity: coarse composites carry gangue with them, so the product is a pre-concentrate, not a final concentrate.
Bio-processingbiological
Certain bacteria and archaea make a living oxidising iron and sulphur. In doing so they regenerate ferric iron and acid, and ferric iron dissolves sulphide minerals. The organisms do not attack the metal — they maintain the chemistry that does, continuously and without a reagent bill.
It works on sulphides. Oxide, silicate and carbonate hosts are largely untouched by it, and a tailing that has weathered in air for decades may have lost the very sulphide the organisms need. Acid-consuming gangue — carbonate especially — can neutralise the system faster than the bacteria can acidify it. Whether a given dump still holds leachable sulphide is a mineralogical question, and it is exactly the question no assay answers.
Choosing the lixiviantchemical
Leaching is not one technology. The solvent decides the cost, the permit, the residue and half the public objection, and the last twenty years have produced real alternatives to the two reagents the industry was built on — cyanide for gold, sulphuric acid for copper.
| Lixiviant | Targets | Conditions | Why it is chosen | What it costs | Status |
|---|---|---|---|---|---|
| Sulphuric acid | Cu, U, Ni, Zn oxides | ambient, pH <2 | cheap, understood, works in a heap | consumed by carbonate gangue; leaves an acid residue | commercial |
| Cyanide | Au, Ag | ambient, pH 10–11 | unmatched selectivity for gold at very low grade | toxicity, permitting, destruction circuit, social licence | commercial |
| Thiosulfate | Au | ambient, mildly alkaline | no cyanide; handles carbonaceous ore that robs cyanide | reagent loss and recycle complexity | commercial |
| Glycine | Au, Cu, Ni, Co, Zn | ambient–60 °C, alkaline | an amino acid: benign, recyclable, does not attack silicate gangue | slower; needs a recovery step that returns the glycine | demonstrated |
| Chloride | Cu (chalcopyrite), Au, PGM | ambient–elevated, saline | attacks chalcopyrite, which acid heaps famously do not | corrosion; materials of construction | demonstrated |
| Ammonia / ammoniacal | Cu, Ni, Co | ambient, alkaline | ignores carbonate gangue that would eat acid | volatility, containment, odour | commercial |
| Deep eutectic solvents | base & precious metals | elevated | tunable selectivity, very low volatility | reagent cost and recycle unproven at scale | laboratory |
Glycine deserves the attention it is getting. It is alkaline, so it does not dissolve the silicate and carbonate gangue that makes acid leaching of low-grade waste uneconomic — the reagent goes to the metal instead of to the rock. It is recoverable and re-usable, non-toxic and biodegradable, and it will take copper, gold, nickel, cobalt and zinc. That combination is unusual. It is also slower than the reagents it would replace, and the economics turn on how completely the glycine is recovered rather than on how fast the metal dissolves.
Getting the metal out of the solutionsolution recovery
Leaching produces a dilute, dirty liquor, not a product. Every heap-leach operation on Earth is followed by a second plant whose only job is to concentrate and purify what the first one dissolved — and for a reprocessing project this half is often the larger risk, because waste liquors carry impurities that fresh ore liquors do not.
Thermal treatment, and what it destroys
Roasting and smelting change the phase an element sits in. That is the point — and it is also permanent. A carrier mineral may simply not exist any more in the material a roaster produced, which constrains what can ever be done with that residue.
This is where knowing the historical flowsheet stops being background and becomes a constraint. But it applies to the stream that went through the stage, not to every waste body at the same mine: a plant that roasted a flotation concentrate left the flotation tailings untouched.
Water and residue management
Mineral deportment — the number that matters more than the assay
Selective hybrid recovery
Rather than chemically treating an entire waste mass to recover a small fraction of it, first establish whether cheap physical separation can reject a substantial barren fraction, and treat only what is left.
The condition it depends on, and it is not a detail: the physical stage must not reject the valuable mineral along with the barren fraction. In a flotation tailing the mineral is often locked — which is precisely why it was left behind — and locked grains follow the gangue. Whether this works for any given waste body is a question for a separation test on real material, not for a model.
We publish no mass-rejection figure, no recovery percentage, no water saving and no cost, because none has been measured.
Value that is not a metalphysical & chemical
A waste facility can pay for its own removal without anyone recovering a metal from it. These routes are unglamorous, they move enormous tonnages, and for a low-grade dump near a market they are frequently the only ones that close.
Recovery is not the only objective
A route recovering 95% at very high cost can be worse than one recovering 75% with a far smaller processing burden. The eventual measure has to weigh metal recovered against mass processed, energy, water, reagents, residue generated, capital and operating cost, and what the permits allow — and in the end express it per kilogram of material actually recovered.
We do not calculate that today, for any asset, because it needs test data that does not exist yet.
Who actually does what in this industry
Three different businesses get spoken about as if they were one, and confusing them is how a reprocessing idea ends up addressed to the wrong company.
| Role | What it sells | How it earns | Examples |
|---|---|---|---|
| Equipment & flowsheet suppliers | Engineering, machines, testwork, automation, service. Crushing, grinding, classification, flotation, thickening, filtration, tailings handling — the whole plant. | Selling and servicing the plant. They do not usually take ownership of a waste body or of the metal recovered from it. | Metso, FLS (formerly FLSmidth) |
| Retreatment operators | Nothing. They own or lease the residue and sell the metal. | Waste in, metal out, at enormous scale and very low unit cost. | DRDGOLD, Pan African Resources |
| Selection layer | Which waste bodies are worth anyone's attention, on what evidence, and what should be measured next. | Deciding where the other two should be pointed. | where GeaSpirit sits |
This page exists because of the third row, not the first. GeaSpirit does not design plants and does not intend to. Understanding what happens after screening is what makes a screening judgement worth anything — recommending a facility without knowing whether any route could plausibly treat it is how a shortlist becomes a liability.
The economics: cost per tonne is the adversary
A primary mine can carry an expensive flowsheet because the feed is rich. A waste body usually holds a small amount of value spread through millions of tonnes, and there the arithmetic runs the other way: nothing can be spent per tonne that the tonne does not return. Everything below is a way of spending it.
The operators who have made this work did not find an exotic technology. They combined enormous throughput, a conventional and well-understood circuit, mechanisation, short pumping distances and a low reagent bill — publicly citing the absence of regrinding and low reagent consumption among the reasons a low-grade retreatment plant stands up at all. The lesson is not that reprocessing needs better chemistry. It is that it needs fewer things happening per tonne.
The question worth asking
Two waste bodies can assay the same and be worth entirely different things.
So the useful question is not can a better technology be invented? — that costs years and millions, and Metso and FLS are already doing it. It is:
can a waste body be found where a simple technology that already exists is enough?
That is a search problem over evidence, which is what GeaSpirit is. The asset worth finding is not the richest one. It is the intersection of large tonnage, a valuable enough element, a known carrier mineral, decent liberation, a strong physical contrast to separate on, little regrinding, few reagents, recyclable or no water, and a buyer within haulage distance. Miss any one of those and grade will not rescue it.
Liberation and mineral contrast are measurements, not inferences. A carrier mineral reported at the source deposit tells you what to test for; it does not tell you the grain is free, or that it will answer to a magnet in this material. Until that is measured, the correct value for how hard a residue would be to treat is unknown — and GeaSpirit records it as unknown rather than as promising.
The selection map
Nothing on this page is chosen from a menu. The route follows from what the material is, and the diagram below is the order in which the questions have to be answered. Read left to right: each branch is a measurement, not a preference.
Maturity, stated plainly
A page that lists a laboratory result beside a technology treating a hundred thousand tonnes a day, in the same typeface, is misleading by layout alone. Every route named above carries one of these four labels, and they mean what they say.
| Label | What it means | What you may conclude |
|---|---|---|
| commercial | operating at production scale, on real feed, for years | engineering risk is manageable; the question is whether it suits this material |
| demonstrated | proven at industrial or large pilot scale, limited number of installations | viable, but expect to fund the learning curve |
| pilot | continuous operation beyond the bench, not yet at production scale | promising; do not build a business case on it alone |
| laboratory | batch results under controlled conditions | interesting; treat published recoveries as an upper bound |
The labels describe the technology, never a facility. A commercial technology applied to an untested material is still an untested proposition.
Can one process do everything?
It is the right question to ask and the answer is no — not for a reason of engineering effort, but for one of physics. What can be recovered from a material is governed by deportment: which mineral actually hosts the metal, how big those grains are, and what they are locked inside. Two dumps assaying an identical 0.3% copper need opposite flowsheets if one carries it as chalcocite at 200 µm and the other as chalcopyrite locked in silicate at 15 µm. No solvent, no cell and no sorter changes that, because the difference is in the rock and not in the machine.
So a universal process is not available. A universal sequence is — and that is where the real gain of the last decade has been.
Reject early · concentrate coarse · leach small
Every expensive step in a plant scales with the mass that reaches it, and every low-grade waste project dies because too much mass reaches the expensive steps. The winning move is not a better reactor. It is arranging for 90–98% of the feed to never see one.
Stage 1 — reject. Sensor sorting at coarse size, on a conveyor, no water. Throw away what demonstrably carries nothing. Cheap per tonne precisely because it is crude.
Stage 2 — pre-concentrate coarse. Coarse-particle flotation or enhanced gravity, at a size that dewaters by screening. The reject leaves as a dry stack rather than as a slurry needing a dam.
Stage 3 — grind only the concentrate. Ultrafine milling applied to 2–10% of the original mass instead of all of it. This single reordering is what makes the energy arithmetic survive.
Stage 4 — leach small, benign, and recycle the reagent. A small, concentrated stream is where an alkaline lixiviant such as glycine becomes affordable, and where recovering the reagent is worth the equipment.
Stage 5 — recover from solution. Ion exchange or SX, then electrowinning.
Every one of those five stages is commercially available today. Nothing here is invented. What is genuinely modern is the order, and the discipline of sizing the plant around rejection rather than around throughput. It is polyvalent in the way that matters: the sequence holds for copper, gold, zinc, cobalt and rare earths, while the settings inside each stage are tuned per site. It is modular, so it can be skid-mounted and moved between dumps that are each too small to justify a fixed plant — which is the actual economic shape of mine waste.
The bottleneck is selection, not metallurgy
Reprocessing projects rarely fail because the flowsheet was wrong. They fail earlier: money is spent on testwork at a site that was never a candidate, because the only cheap information anyone had was an assay — and an assay cannot distinguish the two dumps in the first paragraph of this section.
The gap is a cheap, standardised, deportment-first screen: automated mineralogy on a correctly taken sample, a sequential extraction to show what is actually soluble, and a size-by-size assay to show where the metal sits. Together they identify the family of flowsheet a material belongs to, before anyone commissions a pilot. That is small money against a testwork programme, and it is the measurement that decides whether the testwork is worth doing at all.
GeaSpirit does not build plants and does not intend to. What it can do is establish, from public evidence, which facilities are worth that screen — and say honestly when the remote evidence is exhausted and the next real step requires touching the material. That is a selection instrument, and selection is the step the sector currently does worst.
That GeaSpirit has invented a unit operation; that any of these routes is proven on any specific facility in the warehouse; or that a percentage recovery can be predicted from anything short of testwork on real material. Every number drawn on this page is illustrative of a mechanism. None of them is a measurement of a place.
What GeaSpirit does with this — and what it refuses to do
GeaSpirit does not select a process for a waste body. Choosing a flowsheet remotely would need particle-size distribution, liberation, mineral deportment, magnetic and electrical response and bench recovery data, and none of that is published by any register anywhere: it comes from automated mineralogy on physical material.
What the evidence can do is eliminate. So each route on each facility carries a state, privately, and none of them is a recommendation:
What has to be measured before any route can be chosen
Three situations, and why they are not the same
Coarse waste rock
Particles large enough to be measured individually. Sensor sorting and physical preconcentration are genuinely plausible, and the question is grade and tonnage.
Fine flotation tailings
Fine, and probably poorly liberated — that is often why the material is there. No route can be chosen without mineralogy and liberation data, and a dry preconcentration assumption is exactly the wrong instinct.
Residue after thermal treatment
The mineral phases have changed. The historical process becomes the decisive evidence for what remains possible, and it applies to that stream alone.
Sources
- Wills’ Mineral Processing Technology, 8th ed. (Wills & Finch) — standard reference for comminution, liberation, flotation, gravity and magnetic separation.
- Vick, Planning, Design and Analysis of Tailings Dams (1990); Blight, Geotechnical Engineering for Mine Waste Storage Facilities (2010) — tailings properties and bulk density ranges.
- Reviews of critical-metal recovery from mine and mineral-processing tailings, and of flotation applied to tailings reprocessing, in the peer-reviewed metallurgical literature.
- Reviews of dry and triboelectrostatic separation, and of sensor-based ore sorting, for the particle-size limits described above.
- Work on closed water loops, thickening, filtration and dry stacking in mine-waste management.
- Eriez / Woodgrove — published operating data on fluidised-bed and staged coarse-particle flotation.
- Rawlings, D. E. & Johnson, D. B. — Biomining; reviews of heap bioleaching and tank biooxidation at commercial scale.
- Oraby, E. A. & Eksteen, J. J. (Curtin University) — peer-reviewed work on glycine leaching of copper, gold, nickel and cobalt.
- Aylmore, M. G. — reviews of thiosulfate as an alternative to cyanide, including commercial operation.
- Ritcey, G. M. & Ashbrook, A. W. — standard references on solvent extraction and ion exchange in hydrometallurgy.
- Napier-Munn, T. et al. — Mineral Comminution Circuits; comminution energy and circuit design.
- Power, I. M. et al. — carbon mineralisation in ultramafic mine tailings.
- Gordon, R. & van Deventer, J. — alkali-activated binders and geopolymers from tailings and slag.
- Provis, J. L. — supplementary cementitious materials and their qualification for use.
- Gy, P. — sampling theory; the reason a deportment screen depends on how the sample was taken.
Where a limit depends on the material — and most do — this page says so rather than quoting a universal number. No figure here is presented as applying to any particular waste body.